Vertical Liquid Chlorine
For Chlorine and other Toxic, Liquefied Gases

Under normal atmospheric conditions chlorine (CL2) is a greenish, yellow gas with a biting penetrating odor. It is nonflammable, but it supports combustion at higher temperatures. Chlorine, like other halogens, is highly reactive. When it reacts with water, it forms hydrochloric and hypochlorous acids, both of which are highly corrosive. Chlorine is compressed and liquefied for shipping, storage, and handling because it boils at -30°F at atmospheric pressure.

Chlorine is very reactive and potentially deadly. Liquid chlorine can burn the skin. Inhalation can cause sneezing, coughing, shortness of breath, tightness in the chest, severe restlessness or anxiety as well as nausea and vomiting. Immediate death can occur, as a result of suffocation. Later fatalities can occur as a result of pulmonary edema (fluid in the lungs).

With chlorine being such a hazardous substance, the Chlorine Institute recommends only top outlets, as opposed to bottom outlets, for chlorine storage tanks. This represents a serious restriction in designing a liquid chlorine transfer system from storage tanks to loading facilities or other processes. The Lawrence Vertical Liquid Chlorine pump has been specifically developed for mounting on the top nozzle of the pressurized liquid chlorine tank.

With these considerations in mind, Lawrence has designed its Vertical Chlorine pump for efficient transfers without loss or contamination, high capacities and high heads, full automation and protection, with high reliability and long service life.

The use of a Centrifugal Pump to handle liquid chlorine provides a faster transfer than through padding (pressurizing a vessel with air), and allows the chlorine to be transferred without subjecting the chlorine vessel to the high pressure which padding imposes.

Capabilities:
Flows to 800 GPM (180 m3/hr)
Heads to 800 ft (244 m)
Temperatures from -60° F to 125° F (-15° C to 52° C)

In addition to liquid chlorine, these pumps can handle anhydrous hydrogen cyanide, phosgene, bromine, sulfur trioxide, and other dangerous liquefied gases which must be contained to satisfy environmental laws and safety regulations.

Design Features

All models are vertical, top entry units to eliminate hazardous side or bottom connections. Liquid chlorine is pumped in both boiling and suppressed conditions. To prevent chlorine gas leakage to the atmosphere, a buffer gas - dry air or nitrogen - is used between the lower and upper sealing element. For a vapor pressure range up to 60 PSIG (4.2 kg/cm2), packing is used. Higher pressures require a specially-developed, mechanical gas seal for the upper box.

An adjustable gland mechanism permits packing tightening from the outside. In case of packing failure, the emergency seal may be pressurized to prevent chlorine leakage.
The instrumentation package provides for a controlled flow of buffer gas to the air chamber. Vapor pressure in tank is reference pressure.
Thermocouples monitor the temperature of the lower packing. Excess heating automatically shuts the pump down.

The excess flow check valve is a feature which stops the flow of liquid chlorine should a line rupture occur above the mounting plate. The ball in the check valve is designed for the capacity output of the pumping equipment. When a line fractures the capacity of the pump increases, and in doing so the ball rises and seats properly in the valve, which stops the flow of liquid chlorine while the pump is operating.

The sudden closing of the check valve creates a high pressure water-hammer effect. The chamber is filled with liquid chlorine gases and when the check valve slams shut the water-hammer shock waves are absorbed by the surge chamber. The shockwaves are kept from passing down the discharge pipe into the the stages of the pumping equipment which could result in fracturing the pump casing internals.

The diffuser casing design completely balances the radial thrust around the entire 360° circumference of the impeller. Regardless of the number of stages used, or the head developed by the pump, the radial load carried by the sleeve bearings is minimal.

The enclosed carbon steel impellers are equipped with sealing surfaces on both the front and back shrouds. For "wet" chlorine applications monel is available, as is stainless steel for toxic services other than CL2. The radial sealing ring surfaces allow variations in impeller clearances without affecting overall performance. Since chlorine is usually pumped when boiling, NPSHA is equal to submergence above the centerline of the impeller minus friction losses in the suction. To avoid pumping down under cavitation conditions, a suction inducer is available on all sizes. It will lower NPSHR and thereby reduce chlorine inventory in the tanks.

  Product Applications

Liquefied Chlorine Gas
Other Toxic Liquefied Gases
Chemical Processing Industry

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